Reaktionen von Übergangsmetallhalogemden mit N-Trimethylsilylhexafluorisopropylidenimin und Lithiumhexafluorisopropylidenimid
Open Access
- 1 July 1987
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 42 (7) , 874-876
- https://doi.org/10.1515/znb-1987-0713
Abstract
WF6 and Me3SiN = C(CF3)2 (1) react to give the black-red crystalline FW [N = C(CF3)2]5 (3). Ti[N = C(CF3)2]4 • 2THF (4) has been obtained by the rection of LiN = C(CF3)2 (2) and TiCl4 in THF. 3 and 4 are sublimeable solids. They have been characterized by mass and NMR spectra as well as by elemental analysis.Keywords
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