Organophosphorus Compounds, XXVI * The Reaction of Diazoketones with Trialkyl Phosphites

Abstract
Diazoketones 1, 8, 10 and 14 react with trialkyl phosphites to give different products depending upon the structure of the diazo compound, the type of the solvent and the nature of the phosphite ester used. Possible reaction mechanisms are discussed and the structural assignements are based on analytical, chemical and spectroscopic results.

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