Facile Reduction of Organometallic Halides with Bis(pentamethylcyclopentadienyl)ytterbium and the X-Ray Structure of (C5Me5)2YbCl(THF)
- 1 July 1989
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 18 (7) , 1309-1312
- https://doi.org/10.1246/cl.1989.1309
Abstract
No abstract availableThis publication has 7 references indexed in Scilit:
- Organolanthanide and organoactinide oxidative additions exhibiting enhanced reactivity. 5. Stoichiometry, kinetic and mechanistic studies of (C5Me5)2YbII.cntdot.OEt2 oxidative-addition reactions and of (C5Me5)2YbIIIR "YbIII-Grignard" reactions with alkyl and aryl halides. Evidence for the dominance of inner-sphere mechanismsOrganometallics, 1989
- Electron-transfer chemistry of (Me5C5)2Yb: cleavage of diorganoperoxide and related chalcogenides to give (Me5C5)2Yb(ER)(L) (E = O, S, Se, or Te; L = a Lewis base). Crystal structure of (Me5C5)2Yb(TePh)(NH3)Organometallics, 1988
- Preparation and chemical behaviour of halodicyclopentadienyl-zirconium(III) and -hafnuim(III)Journal of Organometallic Chemistry, 1985
- Bis(pentamethylcyclopentadienyl)ytterbium(II) as a Lewis acid and electron-transfer ligand. Preparation and crystal structures of [Yb(Me5C5)2(.mu.-CO)xMn(CO)5-x]y (x, y = 2; x = 3, y = .infin.)Inorganic Chemistry, 1984
- Tertiary phosphine complexes of the f-block metals. Preparation of pentamethylcyclopentadienyl-tertiary phosphine complexes of ytterbium(II), ytterbium(III) and europium(II). Crystal structure of Yb(Me5C5)2Cl(Me2PCH2PMe2)Inorganic Chemistry, 1983
- Divalent lanthanide chemistry. Bis (pentamethylcyclopentadienyl) europium(II) and -ytterbium(II) derivatives: crystal structure of bis (pentamethylcyclopentadienyl) (tetrahydrofuran ytterbium(II) -hemitoluene at 176 KInorganic Chemistry, 1980
- Structural characterization of a chloride-bridged lanthanide cyclopentadienyl dimer, bis[chlorobis(methylcyclopentadienyl)yttrium]Inorganic Chemistry, 1975