Photochemical reactions of fluoro-substituted ketones with amines, tetraphenylborates, and organometals: an electron spin resonance study
Open Access
- 15 March 1980
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 58 (6) , 591-598
- https://doi.org/10.1139/v80-091
Abstract
Ammonium ion-pairs, solvent-separated alkali-metal ion-pairs, and Group IVB organometallic adducts of fluoro-substituted ketones were generated photochemically. The structure and the controlling factors for the formation of contact ammonium ion-pair were deduced from the effects of solvent, amine, and fluorine substitution. The effect of fluorine on the formation of the alkali-metal ion-pairs and organometallic adducts was discussed.Keywords
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