Investigations on Butterfly Fe/S Cluster S-Centered Anions (μ-S-)2Fe2(CO)6, (μ-S-)(μ-RS)Fe2(CO)6, and Related Species
- 4 November 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Accounts of Chemical Research
- Vol. 38 (1) , 21-28
- https://doi.org/10.1021/ar030004j
Abstract
This Account describes the formation and chemical reactivities of the novel butterfly Fe/S cluster anions (μ-S-)2Fe2(CO)6 (I), (μ-S-)(μ-RS)Fe2(CO)6 (II), (μ-S-)(μ-RS)[Fe2(CO)6]2(μ4-S) (III), (μ-S-)(μ-RS)[Fe2(CO)6]3(μ4-S)2 (IV), and {(μ-S-)(μ4-S)[Fe2(CO)6]2}2(μ-SZS-μ) (V). It also gives a description of the novel structures, unique properties, and wide applications of the corresponding butterfly Fe/S cluster complexes produced from these anions. Anions I−V along with their products are important in the development of organometallic chemistry, cluster chemistry, catalysis, and material and life sciences.Keywords
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