Anomalous photochromism and photochemical cation-binding control of crowned Malachite Green leuconitrile based on intramolecular electrostatic repulsion

Abstract
A Malachite Green leuconitrile incorporating a crown-ether moiety has been designed, exhibiting anomalous photochromism and photoinduced switching of cation binding on the basis of intramolecular repulsive interaction between its crown-complexed metal ion and photoionized cationic species.

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