Rhodium(i) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks
- 25 October 2006
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 3,p. 269-271
- https://doi.org/10.1039/b612385f
Abstract
Novel rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks were synthesized and the complexes were used as catalysts in rhodium-catalyzed hydrosilylation of α,β-unsaturated ketones to show high 1,4-adduct selectivity.Keywords
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