Trifluoroacetate complexes of cobalt(II), nickel(II), and copper(II) with pyridine-type ligands. Part I. Metal(II) trifluoroacetates and copper(II) complexes
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 897-904
- https://doi.org/10.1039/j19690000897
Abstract
Complexes of the general type CuLx(CF3CO2)2, where x= 2 or 4, L = pyridine, mono-and di-substituted pyridines, quinoline, or isoquinoline, have been prepared and characterised by spectroscopic methods. The complexes are six-co-ordinate with the trifluoroacetate group involved in either mono-or bi-dentate attachment to the copper; this distinction has been made by i.r. studies. Thermal decomposition studies were carried out on these complexes. The resulting complexes were of the general stoicheiometry [CuLx(CF3CO2)2]n where x= 2, 1, or ½ and n= 1, 2, or perhaps 4.Keywords
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