Model description for single-electron transfer in slow-ion–-molecule collisions: Studies for , , and projectiles
- 1 October 1992
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 46 (7) , 3910-3917
- https://doi.org/10.1103/physreva.46.3910
Abstract
We discuss a recently proposed model for describing single-electron transfer in slow- or intermediate-energy-ion–-molecule collisions and present results for the examples of , , and -ion impact. The dynamics of the two active electrons is given by a one-electron potential model, within the framework of the semiclassical close-coupling description, in conjunction with conservation of the norm of the total two-electron wave function. Considerable numerical simplifications occur when the length of the molecular axis is set to zero. It is argued that this model description of ion-molecule collisions is both efficient and remarkably accurate.
Keywords
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