Synthesis and insertion reactions of cationic alkylbis(cyclopentadienyl)titanium complexes
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1610-1611
- https://doi.org/10.1039/c39860001610
Abstract
The electrophilic 14-electron alkyltitanium cations [cp2TiMe]+(cp =η5-cyclopentadienyl) and [ind2TiMe]+(ind =η5-indenyl), accessible via several routes, form stable complexes [cp2TiMe(L)]+ and [ind2TiMe(L)]+, L = NH3, PMe3, pyridine, MeCN, ButCN and readily with CO and ButNC; the insertion of nitriles into titanium–carbon bonds is described.Keywords
This publication has 0 references indexed in Scilit: