Novel C-2 epimerization of aldoses and stereoselective uptake of one of the epimeric aldoses by nickel(II) complexes
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 1001-1003
- https://doi.org/10.1039/c39860001001
Abstract
Aldoses are rapidly epimerized at C-2 in the presence of [Ni(H2O)2(tmen)2]Cl2(tmen =N,N,N′-trimethylethylenediamine) and, of the two C-2 epimers, nickel(II) ions form complexes with only the mannose-type epimers (D-mannose, D-lyxose, and D- or L-rhamnose) stereoselectively.Keywords
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