Synthesis and structural characterization of the first examples of molecular aggregates of barium supported by aryloxide and alkoxide ligands: [HBa5(O)(OPh)9(thf)8] and [H3Ba6(O)(OBut)11(OCEt2CH2O)(thf)3](thf = tetrahydrofuran)
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1349-1351
- https://doi.org/10.1039/c39900001349
Abstract
The reaction of barium granules in tetrahydrofuran with either phenol or t-butyl alcohol yields phenoxide and t-butoxide aggregates that have been characterized in the crystalline state; they share a number of novel structural features, including the presence of a square-based pyramidal core Ba5(µ5-O) supported by µ3 and µ2 phenoxide or butoxide ligands.Keywords
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