α-Stereoselective Tandem Additions to (ortho-Methoxystyrene) Chromium Tricarbonyl
- 1 January 1995
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1995 (01) , 69-70
- https://doi.org/10.1055/s-1995-4865
Abstract
Homochiral (1’R)-(+)-(ortho-methoxystyrene) chromium tricarbonyl undergoes a completely α-stereoselective tandem β-nucleophilic, α-electrophilic addition sequence with t-butyl lithium and methyl iodide to generate, after decomplexation, homochiral (2R)-(+)-2-(ortho-anisyl)-4,4-dimethylpentane.Keywords
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