Preparation of Matsutake Alcohol (1-Octen-3-ol) from a Butadiene Telomer
- 1 June 1976
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 49 (6) , 1701-1702
- https://doi.org/10.1246/bcsj.49.1701
Abstract
A simple preparation of 1-octen-3-ol so called Matsutake alcohol using a butadiene telomer is described: selective hydrogenation of the terminal double bond of 2,7-octadienyl acetate gave 2-octenyl acetate which was converted via palladium-catalyzed allylic rearrangement and hydrolysis into 1-octen-3-ol.Keywords
This publication has 3 references indexed in Scilit:
- Addition reactions of butadiene catalyzed by palladium complexesAccounts of Chemical Research, 1973
- Preparation and properties of some cationic complexes of rhodium(I) and rhodium(III)Journal of the American Chemical Society, 1971
- The Occurrence of Matsutake Alcohol in the Essential Oil of Perilla frutescens Brit.Nippon kagaku zassi, 1962