Pentaco-ordinate silicon compounds in synthesis: regiospecific allylation of aldehydes by use of triethylammonium bis(pyrocatecholato)allylsilicates
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1517-1518
- https://doi.org/10.1039/c39870001517
Abstract
The title compounds, readily prepared from allytrimethoxysilane, pyrocatechol, and triethylamine, react with aldehydes regiospecifically and chemoselectively without catalyst under mild conditions: the allylation takes place even in protic solvents such as ethanol.Keywords
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