Fluorinations with potassium tetrafluorocobaltate(III). Part II. Fluorination of ketones
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 2277-2279
- https://doi.org/10.1039/p19720002277
Abstract
Diethyl ketone, hexafluoroacetone, and hexachloroacetone have been fluorinated over potassium tetrafluoro-cobaltate(III) to give polyfluoroacyl fluorides as the major products. Diethyl ketone was completely cleaved by cobalt(III) fluoride, though heptafluoro-n-propyl methyl ketone gave heptafluorobutyryl fluoride.Keywords
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