Topotactic Electron/Ion Transfer Reactions of Niobium Chalcogenides Nb3X4 with Tunnel Structure
Open Access
- 1 May 1979
- journal article
- research article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 34 (5) , 697-699
- https://doi.org/10.1515/znb-1979-0510
Abstract
Cathodic reduction of Nb3S4 and Nb3Se4 electrodes in electrolytes containing cations of appropriate size results in the formation of ternary phases An+ x/n[Nb3X4]x-. The cations An+ are taken up into empty channels of the rigid lattice framework and exhibit high ionic mobility at room temperature.Keywords
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