The microwave and radiofrequency spectrum of H2S⋅Ar
- 15 February 1985
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 82 (4) , 1674-1681
- https://doi.org/10.1063/1.448399
Abstract
Molecular beam electric resonance spectroscopy has been used to determine the radiofrequency and microwave spectrum of H2S⋅Ar, HDS⋅Ar, and D2S⋅Ar. The electric dipole moment and nuclear hyperfine interactions reflect an angular structure in which the H2S C2 axis is nearly perpendicular to the Ar...S axis, and the H2S and argon are nearly coplanar. The effective argon–H2S center-of-mass distance is 3.977 Å.Keywords
This publication has 12 references indexed in Scilit:
- Electric dipole moments and nuclear hyperfine interactions for H2S, HDS, and D2SJournal of Molecular Spectroscopy, 1984
- The structure of H2S⋅HF and the stereochemistry of the hydrogen bondThe Journal of Chemical Physics, 1982
- Anisotropic intermolecular forcesMolecular Physics, 1982
- CO2–HF: A linear moleculeThe Journal of Chemical Physics, 1981
- Electric dipole moment of SO2 in ground and excited vibrational statesThe Journal of Chemical Physics, 1979
- The structure of water dimer from molecular beam electric resonance spectroscopyThe Journal of Chemical Physics, 1977
- Determination of the structure of ArHClThe Journal of Chemical Physics, 1973
- Electric Dipole Moment of Carbonyl SulfideThe Journal of Chemical Physics, 1968
- Ground-State Molecular Constants of Hydrogen SulfideThe Journal of Chemical Physics, 1967
- Hyperfine Structure in the Microwave Spectrum of HDO, HDS, CH2O, and CHDO : Beam-Maser Spectroscopy on Asymmetric-Top MoleculesThe Journal of Chemical Physics, 1964