Efficient Synthesis of Deoxy and Dideoxy Sugars by a Thio-Mitsunobu Reaction on Unprotected Glycosides
- 1 January 1992
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1992 (04) , 283-284
- https://doi.org/10.1055/s-1992-21340
Abstract
6-Deoxy-gluco- and 3,6-dideoxy-ribo-hexopyranosides were synthesized in two consecutive steps from unprotected β-glucopyranoside derivatives by a highly regioselective thio-Mitsunobu reaction and subsequent desulfurization. In contrast,the α-anomer reacted only at position 6.Keywords
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