Tailor-making of desired assemblies from well-designed monomers: use of calix[4]arene conformers as building blocks
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 8,p. 887-889
- https://doi.org/10.1039/p19930000887
Abstract
Water-soluble, conformationally-immobilized calix[4]arenes with cone and 1,3-alternate conformations (cone-1 and 1,3-alternate-1, respectively) have been synthesized. In aqueous solution cone-1, with a cone-shaped surface, aggregated into micelles with 20–40 Å diameter whereas 1,3-alternate-1, with a cylindrical surface, could not form such aggregates for concentrations up to 0.010 mol dm–3.Keywords
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