The temperature dependence of chemical shielding in diatomic molecules: CO, F2, ClF, HBr, and HCl
- 15 September 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 67 (6) , 2821-2824
- https://doi.org/10.1063/1.435147
Abstract
The temperature dependence of chemical shielding in CO, F2, ClF, HBr, and HCl gas has been measured. The functions σ0(T) and σ1(T) in the virial expansion of chemical shielding σ =σ0(T)+σ1(T) ρ+⋅⋅⋅ are reported here for 13C, 19F, and 1H nuclei. The largest shifts with temperature are observed for F2.Keywords
This publication has 8 references indexed in Scilit:
- Effect of interactions with nonspherical molecules on 129Xe magnetic shieldingThe Journal of Chemical Physics, 1977
- Absolute temperature dependence of chemical shielding of some reference nucleiJournal of Magnetic Resonance (1969), 1975
- Temperature and density dependence of 129Xe chemical shift in rare gas mixturesThe Journal of Chemical Physics, 1975
- Temperature-dependent chemical shifts and isotope shifts in the NMR spectroscopy of carbon monoxideJournal of Magnetic Resonance (1969), 1974
- Proton magnetic shielding studies of pure, gaseous hydrogen bromideJournal of Magnetic Resonance (1969), 1973
- Proton shielding function for hydrogen chlorideMolecular Physics, 1972
- NMR Spectra of ClF3 and ClF: Gaseous Spectra and Gas-to-Liquid ShiftsThe Journal of Chemical Physics, 1964
- Medium Effects in Proton Magnetic Resonance. I. GasesThe Journal of Chemical Physics, 1962