Chemical Shifts in the K X‐Ray Absorption Discontinuity of Arsenic
- 1 May 1976
- journal article
- research article
- Published by Wiley in Physica Status Solidi (b)
- Vol. 75 (1) , 79-83
- https://doi.org/10.1002/pssb.2220750106
Abstract
The K X‐ray absorption discontinuity of arsenic has been studied in the pure element and in several transition metal arsenides. It is observed that the discontinuity shifts towards the low energy side in the arsenides, indicating charge transfer from the metal to the arsenic atoms. The magnitudes |ΔE| of the shifts are found to be smaller than those observed for the arsenic discontinuity in some other compounds, where the arsenic atom is incorporated as a cation.Keywords
This publication has 10 references indexed in Scilit:
- Chemical shifts in X-ray absorption edges and effective nuclear charge. A correlationIl Nuovo Cimento B (1971-1996), 1972
- Chemical shifts in the K-absorption discontinuity of arsenicJournal of Physics C: Solid State Physics, 1972
- Determination of Effective Atomic Charges from the Chemical Shifts of X-Ray Emission LinesThe Journal of Chemical Physics, 1970
- A rule for chemical shifts of X-ray absorption edgesJournal of Physics C: Solid State Physics, 1970
- X-ray spectroscopic study of chemical bonding in NiSe and NiSe2Proceedings of the Indian Academy of Sciences - Section A, 1969
- X-ray spectroscopic study of chemical bonding in MnSe2 and CoSe2Proceedings of the Indian Academy of Sciences - Section A, 1968
- X-Ray spectroscopic evidence for chemical bonding in manganese selenide (MnSe)Proceedings of the Indian Academy of Sciences - Section A, 1967
- X-Ray Absorption Edge Studies of Supported Cobalt CatalystsPublished by Springer Nature ,1963
- Bestimmung von Atomladungen in Molekülen mit Hilfe der RöntgenemissionsspektrenPhysica Status Solidi (b), 1962
- A linear dependence of energy levels on the valency of elementsCollection of Czechoslovak Chemical Communications, 1932