Addition of singlet and triplet silylene to buta-1,3-diene
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 637-638
- https://doi.org/10.1039/c39730000637
Abstract
Formation of high-energy silicon atoms by the nuclear recoil technique in the presence of buta-1,3-diene gives rise to silylene consisting of 80% triplet and 20% singlet; both configurations add to buta-1,3-diene to give silacyclopent-3-ene.Keywords
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