Asymmetric synthesis of 2,3-disubstituted oxepanes via acetalization–cyclization of an enantioenriched functionalized allylsilane with aldehydes
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 2537-2538
- https://doi.org/10.1039/a908603j
Abstract
According to the protocol for the acetalization–intramolecular allylsilane cyclization, a new enantioenriched allylsilane, (R)-(E)-7-(dimethylphenylsilyl)undec-5-en-1-ol, in the presence of a variety of aldehydes provided enantioenriched trans-2,3-disubstituted oxepanes stereoselectively.Keywords
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