Crystal Chemistry of Stable and Metastable (Rapidly Quenched) B-Metal Alloy Phases
- 1 January 1968
- journal article
- Published by Cambridge University Press (CUP) in Advances in X-ray Analysis
- Vol. 12, 23-49
- https://doi.org/10.1154/s0376030800005644
Abstract
The crystal structures of elements and alloy phases in the B-metal region (B2(Zn) to B5(As) groups) have been classified into phase fields determined by their position in the periodic table. The limited number of equilibrium phases with element-like, disordered crystal structures and of extended terminal solid solutions has been more than doubled by the addition of metastable phases produced by ultra-rapid quenching from the melt (splat cooling). Strong structural correlations exist. Some high pressure phases have been included; in some cases, a qualitative discussion from the viewpoint of pseudopotential theory is given.Keywords
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