Oxidation of organic substrates catalysed by trans-[RuIII(phen)2(OH)(OH2)][ClO4]2and trans-[RuIII(bpy)2(OH)(OH2)][ClO4]2(phen = 1,10-phenanthroline; bpy = 2,2′-bipyridine)
- 1 January 1987
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 173-175
- https://doi.org/10.1039/c39870000173
Abstract
trans-[RuIII(phen)2(OH)(OH2)][ClO 4]2 and trans-[RuIII(bpy)2(OH)(OH2)][ClO4]2(bpy = 2,2′-bipyridine; phen = 1,10-phenanthroline) are active catalysts for the PhlO and aerobic oxidation of organic substrates; a modified electrode, through adsorption oftrans-[RuIII(phen)2(OH)(OH2)][ClO 4]2, was active in the oxidation of alcohol to give aldehyde (or ketone).Keywords
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