Cyclometallation reactionds. VIII. Binuclear manganese carbonyl complexes derived from azobenzene

Abstract
The binuclear bis-ortho-metallated complex( O C ) ~ M ~ C ~ H ~ N = N C ~ H ~ M ~ ( C O ) ~ - Ihas been obtained from a reaction between MnMe(CO)5 and Mn(C6H4N=NPh)(C0)4; the reactionbetween azobenzene and MnPh(CO)$ affords (PhN-NHC,H4)Mn2(C0)6.

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