Effective kinetic resolution in the asymmetric hydrogenation of α-(hydroxyalkyl)acrylate esters
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 578-579
- https://doi.org/10.1039/c39850000578
Abstract
The title compounds are reduced by H2 and biphosphine–rhodium catalysts with high anti-selectivity; asymmetric catalysts give up to 7 : 1 discrimination between the enantiomers of starting material.Keywords
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