Crystal structures of four complexes of quinquedentate macrocyclic ligands with novel co-ordination geometries containing five-co-ordinate silver(I), six-co-ordinate cadmium(II), six-co-ordinate mercury(II), and seven-co-ordinate cadmium(II)
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 167-168
- https://doi.org/10.1039/c39770000167
Abstract
Metal complexes of two ‘N5’ macrocyclic ligands are five-co-ordinate (distorted pentagonal plane, M = AgI), six-co-ordinate (distorted pentagonal pyramid, M = CdII or HgII), or seven-co-ordinate (pentagonal bipyramid, M = CdII) depending upon the sizes of the metal ion and macrocycle.Keywords
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