Molecular beam photodissociation of TlI: Bond energy and state symmetry
- 15 February 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 66 (4) , 1434-1436
- https://doi.org/10.1063/1.434103
Abstract
A beam of TlI is dissociated with a laser at 299.0 nm. The time of flight of the iodine atoms leads to a bond dissociation energy of 62.1±0.9 kcal/mol. Fragment angular distribution measurements made with a high pressure lamp show that both the 302.5 and the 380 nm bonds of TlI are transitions of mixed parallel and perpendicular symmetries.Keywords
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