Preparation and characterisation of C70Ph9OH; the first fullerene with a single hydroxy group attached to the cage
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 1231-1232
- https://doi.org/10.1039/cc9960001231
Abstract
The fullerenol C70Ph9OH is obtained as a minor product from the reaction of C70Cl10 with benzene/FeCl3and is chiral due to the attachment of a hydroxy group and a phenyl group across the 7,8-bond; this adjacency inhibits free rotation of the 8-phenyl group.Keywords
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