Molecular recognition of anionic substrates. Binding of carboxylates by a macrobicyclic coreceptor and crystal structure of its supramolecular cryptate with the terephthalate dianion
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 62-64
- https://doi.org/10.1039/c39910000062
Abstract
The macrobicyclic polyammonium receptor molecule 1–6H+ binds dicarboxylate substrates with linear recognition and forms with terephthalate a very stable dianion cryptate the crystal structure of which has been determined.Keywords
This publication has 10 references indexed in Scilit:
- Molecular catalysis by polyammonium receptorsPublished by Springer Nature ,2005
- Molecular recognition. 8. Two-point hydrogen-bonding interaction: a remarkable chain-length selectivity in the binding of dicarboxylic acids with resorcinol-aldehyde cyclotetramer as a multidentate hostJournal of the American Chemical Society, 1990
- Supramolecular Chemistry—Scope and Perspectives Molecules, Supermolecules, and Molecular Devices (Nobel Lecture)Angewandte Chemie International Edition in English, 1988
- Polyaza macrobicyclic cryptands: synthesis, crystal structures of a cyclophane type macrobicyclic cryptand and of its dinuclear copper(I) cryptate, and anion binding featuresJournal of the Chemical Society, Chemical Communications, 1987
- Anion Coreceptor Molecules. Linear Molecular Recognition in the Selective Binding of Dicarboxylate Substrates by Ditopic Polyammonium MacrocyclesHelvetica Chimica Acta, 1986
- Supramolecular Chemistry: Receptors, Catalysts, and CarriersScience, 1985
- Molecular Recognition in Anion Coordination Chemistry. Structure, Binding Constants and Receptor‐Substrate Complementarity of a Series of Anion Cryptates of a Macrobicyclic Receptor MoleculeHelvetica Chimica Acta, 1984
- Anion receptor molecules. Chain length dependent selective binding of organic and biological dicarboxylate anions by ditopic polyammonium macrocyclesJournal of the American Chemical Society, 1982
- Coreceptor–substrate binding. Crystal structures of a macrotricyclic ligand and of its molecular cryptate with the cadaverine dicationJournal of the Chemical Society, Chemical Communications, 1982
- Molecular recognition. Anion cryptates of a macrobicyclic receptor molecule for linear triatomic speciesJournal of the American Chemical Society, 1978