Trimethylsilyl and trimethylgermyl group migration from ruthenium to cycloheptatriene: crystal structure of [Ru(SiMe3)(CO)2C7H7(C6F5)(SiMe3)]
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 673-674
- https://doi.org/10.1039/c39740000673
Abstract
Cycloheptadienyl complexes [Ru(MMe3)(CO)2(C7H8MMe3)](M = Si or Ge) are formed on reaction of Ru(MMe3)2(CO)4 with cycloheptatriene; an X-ray diffraction study on [Ru(SiMe3)(CO)2C7H7(C6F5)(SiMe3)] has established an exo-configuration for the migrant SiMe3 group.Keywords
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