Highly γ-Selective Coupling of Siloxyallylbarium Reagent with Carbonyl Compounds and Alkyl Halides

1 January 1993

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 1993 (09) , 686-688
https://doi.org/10.1055/s-1993-22572

Abstract

Siloxyallylbarium reagents, prepared from anhydrous BaI₂ and siloxyallyllithium, reacted with carbonyl compounds and alkyl halides highly selectively at the γ-position in high yields.

Keywords

SILOXYALLYLBARIUM REAGENT
REACTED
BAI
SILOXYALLYLLITHIUM
ANHYDROUS
HIGHLY SELECTIVELY AT THE Γ
SELECTIVE COUPLING

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