Die Reaktivität des [Fe2(μ2‐O)(μ‐acetato)2]‐Strukturelements in Methämerythrin‐Modellverbindungen gegenüber N⊖3 und NCS⊖
- 1 May 1985
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 97 (5) , 415-416
- https://doi.org/10.1002/ange.19850970520
Abstract
Das Enzym Desoxyhämerythrin reagiert mit N und NCS⊖ völlig anders als die Methämerythrin‐Modellverbindungen mit der Teilstruktur 1, LN,N′N″‐Trimethyl‐1,4,7‐riazacyclonoman. Während die [Fe2(μ2‐O)(μ‐carboxylato)2]‐Gruppe des Enzyms intakt bleibt, werden in der Modellverbindung die Carboxylatobrücken und die Oxobrücke ersetzt magnified image . magnified imageKeywords
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