Organosilicon and organotin phosphines and arsines as mono- and poly-dentate ligands to metal carbonyls
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1631-1633
- https://doi.org/10.1039/j19690001631
Abstract
The organometallic phosphines and arsines Me3SnPPh2, Me2Sn(PPh2)2, Me3SiAsMe2, Me2Si(AsMe2)2, MeSi(AsMe2)3, Me3SnAsMe2, and Me2Sn(AsMe2)2 react with nickel, chromium, and molybdenum carbonyls, behaving as mono-, bi-, and tri-dentate ligands as appropriate. The i.r. and 1H n.m.r. spectra of the products are reported and discussed.Keywords
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