Chemical Reactivities of the Cation and Anion of M@C82 (M = Y, La, and Ce)
- 28 January 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (7) , 2143-2146
- https://doi.org/10.1021/ja043986b
Abstract
The chemical reduction and oxidation of [email protected]82 (M = Y, La, and Ce) afford the corresponding anion and cation, respectively, which show unique and interesting chemical reactivities. It is found that the successful reversible gain or loss of electrons by ionization is useful for controlling the stability and reactivity of [email protected]82 toward both nucleophiles and electrophiles.Keywords
This publication has 32 references indexed in Scilit:
- Absorption Spectra of Metallofullerenes M@C82 of LanthanoidsThe Journal of Physical Chemistry A, 2000
- Novel Metal-Free Bis-silylation: C60-Sensitized Reaction of Disilirane with BenzonitrileOrganic Letters, 1999
- Synthesis of the First Adducts of the Dimetallofullerenes La2@C80 and Sc2@C84 by Addition of a DisiliraneAngewandte Chemie International Edition in English, 1995
- Isolation and Characterization of an ESR-Active La@C82 IsomerThe Journal of Physical Chemistry, 1994
- Adduct of C70 at the Equatorial Belt: Photochemical Cycloaddition with DisiliraneJournal of the American Chemical Society, 1994
- Isolation of an ESR-Active Metallofullerene of La@C82The Journal of Physical Chemistry, 1994
- The ionization energies and electron affinities of endohedral metallofullerenes MC82(M = Sc, Y, La): density functional calculationsJournal of the Chemical Society, Chemical Communications, 1994
- Organic chemical derivatization of fullerenes. 2. Photochemical [2 + 3] cycloaddition of C60 with disiliranesJournal of the American Chemical Society, 1993
- Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitalsThe Journal of Chemical Physics, 1985
- 1,1,2,2-Tetrakis(2,6-dimethylphenyl)-1,2-disilacyclopropaneJournal of the American Chemical Society, 1983