Derivatives of cis-NPCl2(NSOCI)2 and (NPCl2)2NSOCl, V / Preparation of NPCl2(NSOPh)2 and (NPCl2)2NSOPh. Reactions of NPCl2(NSOPh)2 with Dimethylamine
Open Access
- 1 September 1976
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 31 (9) , 1216-1218
- https://doi.org/10.1515/znb-1976-0913
Abstract
Reaction of (NPCl2)2NSOCl or (NPCl2)2NSOF with benzene in the presence of AlCl3 yields (NPCl2)2NSOPh. By the same procedure two isomeric forms of NPCl2(NSOPh)2 can be obtained from cis-NPCl2(NSOCl)2. The phenylated products were characterized by IR, mass and 31P NMR spectra. Reactions of one of the isomers of NPCl2(NSOPh)2 with (CH3)2NH yield NPClN(CH3)2(NSOPh)2 (molar ratio 1:2) and NP[N(CH3)2]2(NSOPh)2 (molar ratio 1:6.8). The structures of the amino substituted derivatives were determined by means of 1H NMR measurements.Keywords
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