Nuclear magnetic resonance measurement of sulphur inversion barriers in mer-tris[bis(trimethylsilylmethyl) sulphide]trichloro-rhodium(III) and -iridium(III)
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 13,p. 1160-1163
- https://doi.org/10.1039/dt9760001160
Abstract
Variable-temperature 1H n.m.r. studies of mer-[RhCl3{S(CH2SiMe3)2}3] and mer-[IrCl3{S(CH2SiMe3)2}3] have yielded slightly different sulphur inversion barriers for the two different sulphide ligand environments in these complexes. In both complexes the barrier is somewhat lower for the sulphide ligand trans to chloride.Keywords
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