Electronic Structure and Spectrum of Acetanilide

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Abstract
A molecular orbital calculation has been made for the π electronic structure of acetanilide and related compounds. The simple LCAO procedure, on which the calculation is based, was somewhat modified to allow for electron repulsion. The electronic behaviors of the acetanilide molecule are examined from the viewpoint of the interaction of the phenyl and acetyl groups through the nitrogen atom. From the calculated excitation energies, oscillator strengths, and charge distributions, the features of the observed ultraviolet absorption and other electronic phenomena can be satisfactorily explained. It is shown that the changes of the longer‐wavelength bands in passing from aniline to acetanilide may be interpreted in terms of two electronic effects: (1) a decrease in the tendency of the nonbonding electrons at the nitrogen atom to migrate into the benzene ring; (2) an extension of conjugation. The electronic properties in the ground state are shown to be explicable by taking account of the former effect.

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