Nonenzymic model of the dioldehydratase reaction. Initiation of conversion of ethylene glycol into acetaldehyde on anaerobic photolysis of organocobalamins in the presence of SH-compounds
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 592-593
- https://doi.org/10.1039/c39780000592
Abstract
Anaerobic photolysis of adenosyl- and methyl-cobalamins in an aqueous KCl–HCl buffer (pH 2·0) in the presence of SH-compounds (e.g. dihydrolipoic acid amide) causes conversion of ethylene glycol into acetaldehyde, and provides a model for the dioldehydratase enzymic reaction.This publication has 0 references indexed in Scilit: