Palladium-catalysed regio- and stereo-selective synthesis of allylic amines
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1498-1500
- https://doi.org/10.1039/c39920001498
Abstract
3-Vinyl-2,6-dioxacyclohexan-1-ones 1, by treatment with N-tosyl or N-aryl isocyanates and a catalytic amount of Pd0, are converted into N-tosyl- and N-aryl-3-vinyl-2-aza-6-oxacyclohexan-1-ones 2 in good yields and with unique stereoselectivity.Keywords
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