The Reaction of Methyl Radicals with Molecular Hydrogen
- 1 November 1974
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 52 (21) , 3665-3670
- https://doi.org/10.1139/v74-547
Abstract
Mixtures of neopentane and hydrogen were pyrolyzed in a flow system at 826–968 K and 27–400 mm Hg. Measurements of the yields of CH4 and C2H6 at various conditions enabled calculation of the rate constant for[Formula: see text]at 926 and 829 K. The Arrhenius plot of these and earlier measurements from 372 to 1370 K is a curve, which can be represented by[Formula: see text]Keywords
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