BINOL catalyzed enantioselective addition of titanium phenylacetylide to aromatic ketones
- 21 September 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 21,p. 2448-2449
- https://doi.org/10.1039/b408654f
Abstract
An enantioselective addition of titanium phenylacetylide to ketones, promoted by BINOL, is described; this new enantioselective protocol gives high enantiomeric excess (up to 90% ee) with aromatic ketones using a simple procedure without pyrophoric or expensive reagents.Keywords
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