Dispiroketals in Synthesis: Preparation of a Stable, Sterically Demanding Glyceraldehyde Ketal and Diastereoselective Reactions with Simple Organometallic Reagents
- 1 January 1992
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1992 (1/2) , 52-54
- https://doi.org/10.1055/s-1992-34153
Abstract
A preparation of the novel dispiroketal of D-glyceraldehyde is described. The diastereoselective addition of various organometallic reagents proceeds with anti selectivity due to the large steric bulk of the dispiroketal.Keywords
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