Enantiocontrolled synthesis of (+)-aphanorphine from (R)-O-benzylglycidol: assignment of absolute configuration
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1591-1592
- https://doi.org/10.1039/c39890001591
Abstract
Aphanorphine, a novel 3-benzazepine alkaloid isolated from the freshwater blue–green alga Aphanizomenon flos-aquae, has been synthesized in the antipodal forms starting from (R)-O-benzylglycidol to establish the absolute configuration of the natural product as (1R, 4R).Keywords
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