[Me2Si] Ansa bridged complexes of permethyltitanocene: synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character †
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 9,p. 1365-1368
- https://doi.org/10.1039/a900173e
Abstract
A series of permethylated [Me2Si] ansa bridged titanocene complexes has been synthesized and structurally characterized by X-ray doffraction; the dialkyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me3CH2)]TiR.Keywords
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