Photolysis of dioxiranes in the presence of a nitroxide radical scavenger: the intermediacy of radical anion and diyl species in the production and trapping of methyl and trifluoromethyl radicals
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 771-773
- https://doi.org/10.1039/c39910000771
Abstract
Electron transfer between dioxiranes 1 and nitroxide 2 affords the dioxirane radical anion–oxoammonium cation pair, which generates methyl radicals that are trapped by the nitroxide.Keywords
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