Tetranuclear Copper(I)-Based Infinite One-Dimentional Chain Complex. Synthesis and X-Ray Crystal Structure of {[Cu2(μ-3-methylpyridazine)2(μ-pyrazine)3](ClO4)2}∞
- 1 April 1991
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 20 (4) , 623-626
- https://doi.org/10.1246/cl.1991.623
Abstract
The title copper(I) compound has been isolated, whose X-ray crystallographic structure shows a rare polymerization mode in which the tetranuclear copper units, composed of three- and two-coordinate copper(I) atoms, are linked by pyrazines. This gives a cyclic voltammogram and a chrage transfer band characteristic of the polymeric structure in the solid state.Keywords
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