Déplacements Homolytiques Intramoléculaires : 15 ‐ Additions Radicalaires A des Peroxydes β‐Éthyléniques
- 1 January 1987
- journal article
- research article
- Published by Wiley in Bulletin des Sociétés Chimiques Belges
- Vol. 96 (10) , 769-774
- https://doi.org/10.1002/bscb.19870961007
Abstract
Free radical additions of cyclohexane, tetrahydrofuran, methyl propanoate, acetonitrile, dichloromethane to allyl t‐butyl peroxide, t‐butyl 2‐methyl prop‐2‐enyl peroxide, t‐butyl 2,2‐dimethyl prop‐2‐enyl peroxide and t‐butyl 3‐methyl but‐2‐enyl peroxide have been studied. Every step of the induced decomposition has been analyzed in terms of steric and polar effects, but no one itself could explain the observed results.Keywords
This publication has 8 references indexed in Scilit:
- Deplacements homolytiques intramoleculaires. 12-decomposition induite de peroxydes ethyleniques : influence de la longueur de la chaineTetrahedron, 1986
- Déplacements Homolytiques Intramoléculaires 10-Additions Radicalaires À des Peresters γ-Insatures Influence de Divers Facteurs Sur la Formation D'Esters CycliquesBulletin des Sociétés Chimiques Belges, 1986
- Deplacements homolytiques intramoleculaires : V - epoxy-2,3 propanation des acides et derives par thermolyse du peroxyde d'allyle et de t-butyleTetrahedron, 1985
- Intramolecular homolytic displacements 7 — Free radical additions to unsaturated peroxy compounds : Synthesis of oxygenated heterocyclesTetrahedron, 1985
- Rate constants for the formation of oxiranes by γ-scission in secondary β-t-butylperoxyalkyl radicalsJournal of the Chemical Society, Perkin Transactions 2, 1984
- Formation of CC Bonds by Addition of Free Radicals to AlkenesAngewandte Chemie International Edition in English, 1983
- Which Factors Determine the Reactivity and Regioselectivity of Free Radical Substitution and Addition Reactions?Angewandte Chemie International Edition in English, 1982
- A Series of Tertiary Butyl Peresters Showing Concerted DecompositionJournal of the American Chemical Society, 1958